Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 43, Pages 13314-13318Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707323
Keywords
acid chlorides; alkenes; boron; copper; homogeneous catalysis
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Funding
- Indiana University
- National Institutes of Health [1R01GM114443]
- ACS-PRF [54422-DNI]
- Vice Provost for Research through the Research Equipment Fund
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A method for the copper-catalyzed borylacylation of activated alkenes is presented. The reaction involves borylcupration of the alkene, followed by capture of the generated alkyl-copper intermediate with an acid chloride. The reactions operated with low catalyst loading and generally occurre within 15min at room temperature for a range of activated alkenes. In the case of vinyl arenes, enantioselective borylacylation was possible.
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