Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 74, Pages 10279-10282Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05885c
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Funding
- National Natural Science Foundation of China [21672140, 21672136, 21302123]
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The synthesis of an iodine-doped sumanene, which represents the first example of halogen-doped buckybowls, is described. Pristine trithiasumanene, trisilasumanene and the hitherto unknown parent triselenasumanene, three interesting heterobuckybowls with significant synthetic challenges, were efficiently prepared from the iodine-doped sumanene through non-pyrolytic conditions. This work demonstrates the high potential of hypervalent iodines embedded in extended pi-conjugated systems for the synthesis of novel curved and planar polycyclic aromatic hydrocarbons.
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