Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 74, Pages 10299-10302Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05758j
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Funding
- National Natural Science Foundation of China [21372139, 21772108]
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alpha-Amino acids are among the most common biologically active molecules in nature, and their functionalization has attracted much attention. In this communication, a novel, efficient and general visible-light photocatalytic decarboxylative monofluoroalkenylation of N-protected alpha-amino acids with gem-difluoroalkenes is reported, affording the corresponding alpha-amino monofluoroalkenes which might find applications in medical chemistry and materials science. The reaction proceeded at room temperature with high efficiency and tolerance of various functional groups.
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