Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 74, Pages 10326-10329Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06048c
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Funding
- National Natural Science Foundation of China [21525208, 21272231]
- new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
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Rhodium(III)-catalyzed mild benzylic alpha-fluoroalkenylation of 8-methyl-quinolines with gem-difluorostyrenes has been developed. This reaction occurred via C-H activation and C-F cleavage and is applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereoselectivity.
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