Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 74, Pages 10306-10309Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05014c
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- Harvard
- NIH [GM-115815]
- NSF [1541959]
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We report the isolation of a roomtemperature stable dipyrromethene Cu(O-2) complex featuring a side-on O-2 coordination. Reactivity studies highlight the unique ability of the dioxygen adduct for both hydrogen-atom abstraction and acid/base chemistry towards phenols, demonstrating that side-on superoxide species can be reactive entities.
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