Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 82, Pages 11334-11337Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07024a
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Funding
- National Natural Science Foundation of China [21574077, 21304055]
- Fundamental Research Funds for the Central Universities [GK201501002]
- MEXT, Japan [17H01218]
- Grants-in-Aid for Scientific Research [17H01218] Funding Source: KAKEN
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A highly redox-active building block, bicarbazole, is developed as a monomer for designing crystalline porous covalent organic frameworks and is successfully integrated to the vertices of microporous tetragonal frameworks, leading to densely aligned redox-active arrays. The frameworks with large porosity and high accessibility of the redox-active sites exhibit synergistic structural effects and ultrahigh-performance energy storage.
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