Journal
DALTON TRANSACTIONS
Volume 46, Issue 39, Pages 13166-13170Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt01489a
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Funding
- National Research Foundation of Korea (NRF) [NRF-2016R1A5A1009405, NRF-2017R1A2B4005441, NRF-2017R1A2B4008691, NRF-2015R1C1A1A02036917]
- UNIST [1.170009.01]
- DGIST R&D Program - Ministry of Science, ICT & Future Planning [17-BD-0403]
- National Research Council of Science and Technology [DRC-14-3-KBSI]
- Korea Institute of Science and Technology Information [KSC-2017-C2-0008]
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Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)](2+) complex via an anion effect. Our crystallo-graphic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)(2) produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)(2).
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