4.8 Article

Three-Dimensional Hierarchical Architectures Derived from Surface-Mounted Metal-Organic Framework Membranes for Enhanced Electrocatalysis

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 44, Pages 13781-13785

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201708385

Keywords

carbon nanotubes; melamine sponge; membranes; surface-mounted MOFs; ZIF-67

Funding

  1. National Basic Research of China (973 Program) [2013CB632404]
  2. National Natural Science Foundation of China [21473090, U1663228]

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Inspired by the rapid development of metal-organic-framework-derived materials in various applications, a facile synthetic strategy was developed for fabrication of 3D hierarchical nanoarchitectures. A surface-mounted metal-organic framework membrane was pyrolyzed at a range of temperatures to produce catalysts with excellent trifunctional electrocatalytic efficiencies for the oxygen reduction, hydrogen evolution, and oxygen evolution reactions.

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