4.7 Article

Single Ni sites distributed on N-doped carbon for selective hydrogenation of acetylene

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 84, Pages 11568-11571

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc04820c

Keywords

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Funding

  1. National Key R&D Program of China of YFA [0208300]
  2. National Natural Science Foundation of China [21522107, 21671180, 21521091, 21390393, U1463202]
  3. National Synchrotron Radiation Laboratory in Beijing
  4. National Synchrotron Radiation Laboratory in Shanghai

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We prepared single Ni atoms embedded in an N-doped carbon catalyst with the assistance of metal organic frameworks. The dispersion of Ni atoms was verified by taking X-ray absorption fine structure measurements. Under the typical conditions for hydrogenation of acetylene, this single-site heterogeneous catalyst showed great potential as an alternative to Pd-based materials.

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