Journal
CHEMISTRY LETTERS
Volume 46, Issue 11, Pages 1597-1600Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170706
Keywords
Photoredox catalysis; Glycine derivatives; Mannich reaction
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Funding
- Japan Society for the Promotion of Science (JSPS)
- WPI program (iCeMS, Kyoto University)
- KAKENHI program
- Shiseido Female Researcher Science Grant
- Grants-in-Aid for Scientific Research [16H06356] Funding Source: KAKEN
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Herein, we demonstrate that a visible-light photoredox catalyst and metal catalyst can catalyze the Mannich-type reaction between N-aryl glycine ester and silyl enol ether. The combination of 5-aminofluorescein and InBr3 facilitates the functionalization of N-aryl glycine derivatives under mild reaction conditions without stoichiometric amounts of chemical oxidant (e. g. DDQ, t-BuOOH).
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