Journal
CRYSTAL GROWTH & DESIGN
Volume 17, Issue 11, Pages 6132-6137Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b01322
Keywords
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Funding
- NSF [DMR-1606826]
- Welch Foundation [AX-1730, AX-1593]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1606826] Funding Source: National Science Foundation
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A hydrogen-bonded organic framework (HOF), HOF-11, has been successfully prepared by the slow diffusion of hexane into a tetrahydrofuran solution of tris(4-carboxyphenyl)amine (TCPA). HOF-11 has been characterized by single-crystal and powder X-ray diffraction analysis, which is composed of TCPA ligands connected by the intermolecular hydrogen-bonding interactions in the carboxylic group dimer, showing 11-fold interpenetrated three-dimensional hydrogen-bonded networks in a (10,3)-b topology with the pore size of 6.2 x 6.8 angstrom(2). The permanent porosity of degassed HOF was demonstrated by virtue of the CO2 sorption and selective gas adsorption.
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