Journal
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
Volume 102, Issue -, Pages 263-272Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2017.07.022
Keywords
Graphene oxide (GO); Cement based composites; Hydration and microstructures; Calcium-silicate-hydrate (C-S-H)
Funding
- Natural Science Foundation of China [51678366]
- Shenzhen Fundamental Research Funding [JCYJ20160422092836654]
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Graphene oxide (GO) has been utilized to strengthen composite materials. In this study, the effects of GO on hydration degrees, macro-mechanical strength and calcium-silicate-hydrate (C-S-H) structure of cement based composites were investigated through comprehensive experimental tests. In addition, the aggregation mechanism of GO was verified by alkaline solution simulations, using Ca(OH)(2) and NH3 center dot H2O. Based on the experimental results, it was found that the 3-day and 7-day compressive strengths of cement based composites with 0.2 wt% of GO were increased by 35.7% and 42.3%, respectively as compared to the control. Moreover, the C-S-H structure of cement paste with GO was not observed to have undergone any change via qualitative and quantitative analyses combined with FT-IR, XRD and Si-29-NMR. Besides, the test results of TGA, DTG and Si-29-NMR showed that the hydrated degree of cement paste increased to 10.4% at 28 days when incorporating with 0.1% of GO. (C) 2017 Elsevier Ltd. All rights reserved.
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