Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 54, Pages 13328-13331Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201703726
Keywords
1,5-cyclooctadiene; carbon monoxide; iridium; quartz crystal microbalance; sensing
Categories
Funding
- DFG [PI 178/18-1]
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A thin film of poly-([IrCl(cod)(NHC-onbe)](n)-(propyl-onbe)(m)) (onbe=oxanorbornene) coated on filter paper reacts quantitatively with CO to yield 1,5-cyclooctadiene, the unpleasant smell of which can be detected by the human olfactory system with very high sensitivity. Odorless, but toxic CO is thus translated into the distinct smell of 1,5-cyclooctadiene. Based on malodorogenic sensing it is possible to smell the presence of CO.
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