Journal
DALTON TRANSACTIONS
Volume 46, Issue 36, Pages 12257-12262Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt03154h
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Funding
- Swiss National Science Foundation [200021_159920]
- Swiss National Science Foundation (SNF) [200021_159920] Funding Source: Swiss National Science Foundation (SNF)
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Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynylbenziodoxole (EBX) reagents, which identified a gold(I) picolinate complex as the active catalyst, giving the first mechanistic insights into this transformation.
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