4.7 Article

Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal-organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles

Journal

DALTON TRANSACTIONS
Volume 46, Issue 36, Pages 12010-12014

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt02155k

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Funding

  1. Chevreul Institute, Ministere de l'Enseignement Superieur et de la Recherche, Region Hauts-de-France [FR 2638]
  2. FEDER
  3. Universite Lille 1
  4. Region Nord Pas-de-Calais

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Aluminium-based metal-organic framework MIL-100 was utilized for the capture of actinide ([UO2](2+), Th4+) and lanthanide (Nd3+) cations. The results indicate a very quick sorption process, leading to very high cation uptakes together with selectivity for Th4+.

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