Journal
WASTE MANAGEMENT
Volume 64, Issue -, Pages 161-170Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2017.03.033
Keywords
Incinerated sewage sludge ash; Air pollution control residues; Characterization; Heavy metals; Leachability
Categories
Funding
- Hong Kong Research Grants Council [PolyU 152132/14E]
- Hong Kong Scholars Program [XJ2016035]
- National Natural Science Foundation of China [41602315, 51625903]
- Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences [Z015003]
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The improper disposal of incinerated sewage sludge ash (ISSA) and air pollution control residues (APCR) from sewage sludge incinerators has become an environmental concern. The physicochemical, morphological and mineralogical characteristics of ISSA and APCR from Hong Kong, and the leachability and risk of heavy metals, are presented in this paper. The results showed that a low hydraulic and pozzolanic potential was associated with the ISSA and APCR due to the presence of low contents of SiO2, Al2O3 and CaO and high contents of P, S and Cl (especially for APCR). Although high concentrations of Zn and Cu (especially for ISSA) followed by Ni, Pb and As, Se were detected, a low leaching rate of these metals (especially at neutral and alkaline pH) rendered them classifiable as non-hazardous according to the U.S. EPA and Chinese national regulatory limits. The leached metals concentrations from ISSA and APCR were mainly pH dependent, and metals solubilization occurred mainly at low pH. Different leaching tests should be adopted based on the simulated different environmental conditions and exposure scenarios for assessing the leachability as contrasting results could be obtained due to the differences in complexing abilities and final pH of the leaching solutions. (C) 2017 Elsevier Ltd. All rights reserved.
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