Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 359, Issue 21, Pages 3707-3712Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700780
Keywords
traceless directing group; C-H carbonylation; cobalt; benzylamine; (+)-garenoxacin
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Funding
- National Natural Science Foundation of China [21676253, 21276238]
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The first example of cobalt-catalyzed C(sp(2))-H carbonylation of benzylamines using a traceless directing group is reported, which was successfully applied to the synthesis of N-unprotected iso-indolinones through direct C-H/N-H bonds activation. This protocol tolerates a variety of functional groups and provides a facile and efficient method for the formal synthesis of (+)-garenoxacin.
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