Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 88, Pages 12052-12055Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07175b
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Funding
- European Research Council (ERC) under the European Union's Horizon research and innovation programme [638337]
- European Research Council (ERC) [638337] Funding Source: European Research Council (ERC)
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Only a few studies on the use of halogen bonding in catalysis have been published so far. Herein, (benz) imidazolium-based halogen bond donors are used as catalysts in a Michael addition reaction. The most potent catalyst, a rigid atropisomer featuring two iodo-benzimidazolium moieties, provided a rate acceleration versus a reference compound of ca. 50.
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