Journal
ELECTROCHIMICA ACTA
Volume 257, Issue -, Pages 192-202Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.10.023
Keywords
carbazole; phenothiazine; acridone; electroactive polymer; spectroelectrochemistry
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Funding
- Polish National Science Centre [2012/05/B/ST5/00745]
- Rector of the Silesian University of Technology [04/040/RGJ17/0052]
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In this work we present electropolymerization of monomers of an unusual type using N-linked carbazole units to limit their conjugation. The polymers thus obtained have limited conjugation through the backbone. Using donor-acceptor-donor (D-A-D) and donor-donor-donor (D-D-D) monomers we evaluate the effects of the presence (or absence) of charge transfer states on synthesized electropolymers. The use of a D-A-D monomer resulted in obtaining an ambipolar polymer with quasi-reversible reduction. (C) 2017 Elsevier Ltd. All rights reserved.
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