Journal
CHIRALITY
Volume 29, Issue 11, Pages 663-669Publisher
WILEY
DOI: 10.1002/chir.22765
Keywords
amino acids; diamines; circular dichroism; absolute configuration; enantiomeric excess; chiral amplification
Funding
- Division of Chemistry [CHE-1464547]
- NSF [CHE-1464547]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464547] Funding Source: National Science Foundation
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Three Cu(I) complexes derived from stereodynamic diphosphine ligands were synthesized and used for chirality sensing. The coordination of diamines and amino acids to these complexes generates distinct circular dichroism signals. The chiroptical sensor response allows determination of the absolute configuration and the enantiomeric excess of the analyte at low concentrations. This method is operationally simple, fast, and attractive for high-throughput sensing applications.
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