4.7 Article

Two nanoscale Nb containing polyoxometalates based on {P2W15Nb3O62} clusters and chromium cations

Journal

DALTON TRANSACTIONS
Volume 46, Issue 39, Pages 13345-13348

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt02737k

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Funding

  1. NSFC of China [21601071, 21471027, 51572116]
  2. NSF of Jiangsu Province [BK20160211]
  3. Natural Science Foundation of Jiangsu Normal University [15XLR012]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions
  5. TAPP

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Two novel mixed-addenda Nb/W polyoxometalates are successfully fabricated, and investigated as anode materials for lithium-ion batteries. For the Cs5K4{Cr-3(H2O)(12)[P2W15Nb3O62](2)}center dot 60H(2)O sample, a reversible capacity (466.6 mA h g(-1)) and stable cycle performance are obtained.

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