4.6 Article

Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

Journal

CHEMCATCHEM
Volume 9, Issue 20, Pages 3821-3826

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700779

Keywords

alcohols; organocatalysis; oxidation; oxyfunctionalization; photocatalysis

Funding

  1. European Research Council (ERC) [648026]
  2. European Research Council (ERC) [648026] Funding Source: European Research Council (ERC)

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The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.

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