4.7 Article

Effects of ammonium polyphosphate content on mechanical, thermal and flammability properties of kenaf/polypropylene and rice husk/polypropylene composites

Journal

CONSTRUCTION AND BUILDING MATERIALS
Volume 152, Issue -, Pages 484-493

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2017.07.052

Keywords

Ammonium polyphosphate; Rice husk; Kenaf; Polypropylene; Composites; Mechanical properties; Thermal properties; Flame retardancy properties

Funding

  1. Universiti Teknologi Malaysia (UTM) [7825, 3F302]
  2. Fundamental Research Grant Scheme (FRGS) [7844, 4F525]
  3. Ministry of Higher Education (MOHE)
  4. Research University Grant (RUG) [2544, 10H94]

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This study investigated the effects of ammonium polyphosphate (APP) content on the mechanical, thermal and flammability properties of kenaf/polypropylene (KF/PP) and rice husk/polypropylene (RH/PP) composites prepared by melt mixing technique. Polyethyleneoctene grafted maleic anhydride (POE-g-MAH) has been used as compatibilizer. The PP/KF/APP and PP/RH/APP composites were investigated using flexural and impact tests, scanning electron microscope, thermogravimetric analysis (TGA), differential scanning calorimeter and limiting oxygen index (LOI) test. Flexural modulus of PP/KF/APP and PP/RH/APP composites significantly improved from approximately 1.1-2.5 and 0.9-2.1 GPa, respectively, by the addition of 10 phr APP. The flexural strength of the composites also increased by the incorporation of 10 phr APP. In addition, the impact strength of the PP/RH/APP composites increased above 10 phr APP content. From the TGA results, incorporation of APP into PP/RH and PP/KF composites increased the char residue and thermal stability of the composites. Furthermore, the addition of APP increased the flame retardancy of the PP/ICF/APP and PP/RH/APP composites with a significant increase of LOI at 10 phr. (C) 2017 Elsevier Ltd. All rights reserved.

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