Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 57, Pages 14163-14166Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201703485
Keywords
co-conformation; coordination chemistry; mechanically interlocked molecules; rotaxanes; silver(I) binding
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Funding
- Natural Sciences and Engineering Research Council of Canada
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A novel [2]rotaxane ligand has been prepared that contains a bidentate N,N'-chelate as part of a rigid, H-shaped axle and a 24-membered crown ether macrocycle containing six ether O-atoms and a trans olefinic group as the wheel. This unique interlocked connectivity allows access to a number of different donor sets, which are shown to be capable of binding Ag-I metal ions.
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