Journal
DALTON TRANSACTIONS
Volume 46, Issue 38, Pages 12771-12774Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt02889j
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Funding
- National Natural Science Foundation of China [21571049, 21471045]
- Natural Science Foundation of Henan Province [162300410027, 162300410013]
- Foundation of Henan Educational Committee [14A150022]
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A novel three-dimensional metal-organic framework [Ni-3(BTC)(2)(bpp) (2)(H2O)].3H(2)O (1) based on mixed ligands H3BTC (1,2,4-benzenetricarboxylic acid) and bpp (1,3-bis(4-pyridyl) propane) was obtained under hydrothermal conditions. Crystal structure analysis reveals that 1 is a framework based on cage-like Ni8(()COO)(12) units. Furthermore, long-range magnetic ordering is observed at low temperature.
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