Journal
CRYSTENGCOMM
Volume 19, Issue 38, Pages 5749-5754Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce01295k
Keywords
-
Categories
Funding
- Tarbiat Modares University
Ask authors/readers for more resources
Solvent-assisted linker exchange (SALE) was performed on two pillared metal-organic frameworks (MOFs), [Zn-2(oba)(2)(4-bpdb)](n)center dot(DMF)(2) (TMU-4) and [Zn(oba)(4-bpmb)(0.5)](n)center dot(DMF)(1.5) (TMU-6), to tune their photocatalytic properties. The pillar ligands were successfully replaced in these MOFs to generate daughter MOFs TMU-4' and TMU-6', which possess higher BET surface areas. Moreover, a study was performed to examine the photocatalytic performance of these parent and daughter MOFs in photoreduction of Cr(VI) under visible light irradiation. Finally, the reduction mechanism was investigated by using various scavengers including AgNO3, t-butyl alcohol, BQ and ammonium oxalate.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available