Journal
CHEMCATCHEM
Volume 9, Issue 19, Pages 3627-3631Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700580
Keywords
alkynes; carbene ligands; dimerization; homogeneous catalysis; platinum
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Funding
- National Centre for Research and Development (Poland) [PBS2/A5/40/2014]
- Foundation for Polish Science [POMOST/2012-6/14]
- European Union under the European Regional Development Fund
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New platinum(0) complexes of the general formula [(NHC)Pt(dvtms)] (dvtms=1,3-divinyltetramethyldisiloxane) containing bulky N-heterocyclic carbene (NHC) ligands were prepared, characterized, and found to be catalytically active in the fully regio- and stereoselective dimerization of terminal acetylenes.
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