Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 359, Issue 19, Pages 3347-3353Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700666
Keywords
asymmetric catalysis; enones; perfluoroalkyl groups; phosphines; Rauhut-Currier reaction
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Funding
- 973 Programs [2015CB856600]
- National Natural Science Foundation of China [21372084, 21425205, 21672067]
- Changjiang Scholars and Innovative Research Team in University (PCSIRT)
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The highly enantioselective N-acylaminophosphine-catalyzed challenging asymmetric intermolecular cross Rauhut-Currier reaction of vinyl ketones with beta-perfluoroalkyl enones is described, which provides a facile access to chiral multifunctional compounds bearing a perfluoroalkyl-substituted stereocenter in good yields and ees.
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