4.7 Article

Characterization and properties of CuZrAlTiNi high entropy alloy coating obtained by mechanical alloying and vacuum hot pressing sintering

Journal

ADVANCED POWDER TECHNOLOGY
Volume 28, Issue 10, Pages 2556-2563

Publisher

ELSEVIER
DOI: 10.1016/j.apt.2017.07.006

Keywords

High entropy alloy coating; Vacuum hot pressing sintering; Mechanical alloying; Corrosion resistance; Mechanical property

Funding

  1. Natural Science Foundation of China [51671095, 51372101]
  2. Key Research Development Program of Shandong Province of China [2015GGx102016]
  3. Taishan Scholars Project of Shandong Province of China [2016-2020]

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CuZrAlTiNi High entropy alloy (HEA) coating was synthesized on T10 substrate using mechanical alloying (MA) and vacuum hot pressing sintering (VHPS) technique. The MA results show that the final product of as-milled powders is amorphous phase. The obtained coating sintered at 950 degrees C is compact and about 0.9 mm in thickness. It is composed of a couple of face-centered cubic (FCC), one body-centered cubic (BCC) solid solutions and AlNi2Zr phase. The interface strength between coating and substrate is 355.5 MPa measured by three point bending test. Compared with T10 substrate, the corrosion resistance of CuZrAlTiNi HEA coating is enhanced greatly in the seawater solution, which is indicated by the higher corrosion potential, wider passivation region, and secondary passivation. The average microhardness of the coating reaches 943 HV0.2, and is about 3.5 times higher than the substrate, which is mainly ascribed to the uniformly dispersed nano-size precipitates, phase boundary strengthening and solid solution strengthening. Moreover, the wear resistance of the coating is slightly improved in comparison with the substrate. (C) 2017 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.

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