Journal
COORDINATION CHEMISTRY REVIEWS
Volume 348, Issue -, Pages 1-24Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2017.07.017
Keywords
Cucurbit[n]uril; Hydroxylated cucurbit[n]uril; Modification; Derivatives; Applications
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Funding
- National Natural Science Foundation of China [21561007, 51463004, 51663005, 21601090]
- Innovation Program for High-level Talents of Guizhou Province [2016-5657]
- Science and Technology Fund of Guizhou Province [2016-1030]
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Cucurbit[n]urils (Q[n]s), a relatively new class of macrocyclic hosts with a rigid hydrophobic cavity and two identical carbonyl-fringed portals, have attracted much attention in supramolecular chemistry. Compared to the chemistry of cyclodextrins and calixarenes, the development of cucurbit[n]uril chemistry has been relatively slow, mainly due to the high chemical stability of Q[n]s, which makes them difficult to functionalize. The discovery of the direct oxidation method to yield perhydroxylated cucurbit[n] urils {(HO)(2n)Q[n]s} greatly promoted Q[n] chemistry, since (HO)(2n)Q[n]s can serve as a platform trigger for the synthesis of many other functionalized cucurbit[n]urils. The resulting products have attracted much attention for numerous potential applications. In this review, we summarize developments based on derivatives of cucurbit[n]urils hydroxylated at the equatorial positions, as well as the potential applications of these molecules. (C) 2017 Elsevier B.V. All rights reserved.
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