4.6 Review

Redox Active Metal- and Covalent Organic Frameworks for Energy Storage: Balancing Porosity and Electrical Conductivity

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 65, Pages 16419-16431

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702919

Keywords

covalent organic framework; conductivity; electrode; metal-organic framework; porosity; redox-active

Funding

  1. Institute of Bioengineering and Nanotechnology, Biomedical Research Council, Agency for Science, Technology and Research

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Porous redox-active metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have emerged as electrode materials for energy storage devices. These porous frameworks have different levels of intrinsic properties such as low solubility, high ionic conductivity (porosity) and low electrical conductivity, all of which are critical parameters when utilised as electrode materials. This Minireview focuses on recent developments of using porous MOFs/COFs as redox active electrode materials for energy storage and strategies to improve their electrochemical performance.

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