4.7 Article

Intrinsic triple-emitting 2D copper thiolate coordination polymer as a ratiometric thermometer working over 400 K range

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 90, Pages 12225-12228

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06815h

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Funding

  1. Agence Nationale pour la Recherche (ANR JCJC FULOR) [ANR-13-JS08-0005-01]
  2. Rhone-Alpes region

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A copper thiolate coordination polymer, [Cu(p-SPhCO2Me)](n), is described and exhibits, under UV, luminescence thermochromism, associated to a unique well-separated triple emission. This compound is the most promising candidate as a ratiometric temperature sensor, working in a wide temperature range, from 100 to 500 K, with a great sensitivity.

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