Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 46, Pages 14411-14416Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706660
Keywords
broadband emission; cationic frameworks; lead halide; light-emitting diodes; photostability
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Funding
- National Natural Science Foundation of China [20501136]
- Recruitment of Global Youth Experts of China
- Science & Technology Commission of Shanghai Municipality [14DZ226110]
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We report a family of cationic lead halide layered materials, formulated as [Pb2X2](2+)[-O2C(CH)(2)CO2-] (X=F, Cl, Br), exhibiting pronounced broadband white-light emission in bulk form. These well-defined PbX-based structures achieve an external quantum efficiency as high as 11.8%, which is comparable to the highest reported value (ca.9%) for broadband phosphors based on layered organolead halide perovskites. More importantly, our cationic materials are ultrastable lead halide materials, which overcome the air/moisture-sensitivity problems of lead perovskites. In contrast to the perovskites and other bulk emitters, the white-light emission intensity of our materials remains undiminished after continuous UV irradiation for 30 days under atmospheric conditions (ca.60% relative humidity). Our mechanistic studies confirm that the broadband emission is ascribed to short-range electron-phonon coupling in the strongly deformable lattice and generated self-trapped carriers.
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