Journal
CERAMICS INTERNATIONAL
Volume 43, Issue 17, Pages 14915-14922Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2017.08.008
Keywords
Flexible ceramics; Zinc oxide tetrapods; Porous network materials; Hybrid metal oxides; Rear earth oxides; Photocatalysis
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Funding
- German Research Foundation (Deutsche Forschungsgemeinschaft) [SFB 1261, AD/183/10-1, GRK 2154]
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The present work demonstrates a very simple and unique strategy for efficient photocatalysis using ZnO ceramic nano- and microtetrapods synthesized by a flame transport synthesis approach. Due to their three-dimensional (3D) morphology, highly porous interconnected networks as flexible ceramics with sufficient mechanical strength can be easily fabricated and efficiently utilized in applications like e.g., photocatalysis, liquid filtering, and membranes. The photocatalytic response can be further enhanced by hybridization of the ZnO tetrapods with different metal oxides which has been explored in detail here. The Cu- and Bi-hybridized ZnO tetrapodal ceramic networks showed the least and highest photocatalytic activities against methylene blue, respectively, whereas, the others exhibited intermediate responses. The observed photocatalytic behaviors of pure and hybrid ZnO tetrapods based flexible ceramic 3D networks are briefly presented and discussed.
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