Journal
CHEMICAL RECORD
Volume 17, Issue 12, Pages 1184-1202Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201700006
Keywords
asymmetric synthesis; hetero-Diels-Alder reaction; inverse-electron-demand cycloaddition; heterocycles
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Funding
- National Natural Science Foundation of China [21290182, 21432006, 21572136]
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In this review, the recent developments in catalytic asymmetric inverse-electron-demand hetero-Diels-Alder reaction, which is recognized as one of the most powerful routes to construct highly functionalized and enantioenriched six-membered heterocycles, are described. The article is organized on the basis of different kinds of electron-deficient heterodienes, including ,-unsaturated ketones/aldehydes, o-benzoquinones, ,-unsaturated imines, N-aryl imines, o-benzoqinone imides, and other aza-olefins.
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