Journal
JOURNAL OF CHEMICAL SCIENCES
Volume 129, Issue 12, Pages 1795-1805Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-017-1380-5
Keywords
Trifluoromethylation; trifluoromethylthiolation; copper complexes; aryl halides; heteroaryl bromides
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Funding
- Chongqing Vocational Institute of Safety Technology [AQJK15-08]
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The copper or complexes as the fluoride sources for the synthesis of trifluoromethylated or trifluoromethylthiolated compounds are reviewed. Compared with the ordinary fluoride reagents, the addition of reactant species in the reaction systems of copper trifluoromethyl or trifluoromethylthio complexes were less, so the reaction systems are relatively simple and easy to operate. In most cases, the trifluoromethylated or trifluoromethylthiolated products were obtained in moderate to excellent yields.
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