Journal
ELECTROANALYSIS
Volume 29, Issue 12, Pages 2810-2817Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201700509
Keywords
Biomimetic sensor; Metal-organic framework; HKUST-1; Electrochemical determination; Catechol
Categories
Funding
- MCTI/CNPq [442609/2014-0]
- Central Laboratory of Electron Microscopy, Federal University of Santa Catarina State (Florianopolis, SC, Brazil)
Ask authors/readers for more resources
In this study, the synthesis and characterization of a Cu-based metal-organic framework (MOF) [Cu-3(BTC)(2)(H2O)(3)](n) (where BTC=benzene-1,3,5-tricarboxylate), known as HKUST-1, were performed. The Cu-MOF was applied in the modification of a carbon paste to obtain a biomimetic sensor for the electrochemical determination of catechol. Kinetic assays confirmed that the Cu-MOF acts as a catalyst for the oxidation of catechol and it can be considered as a catechol oxidase mimetic. Under optimized conditions, the calibration curve for catechol presented a linear range of 8.0x10(-7) to 3.2x10(-5)molL(-1), with detection limit of=1.0x10(-7)molL(-1). The sensor demonstrated good intra-day repeatability and inter-electrode reproducibility (relative standard deviations of 3.8% (n=10) and 4.3% (n=6), respectively). In the selectivity study, an adequate peak-to-peak separation was observed for hydroquinone and uric acid in relation to catechol, demonstrating that this sensor has the potential for use in the simultaneous determination of these compounds. This sensor was successfully applied in the determination of catechol in water samples.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available