Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 35, Issue 12, Pages 1797-1807Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700459
Keywords
1; 2; 3-triazoles; azide-free; hydrazones; diazo compounds; nitrogen heterocycles
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Funding
- National Natural Science Foundation of China [21602202]
- Science Foundation of Zhejiang Sci-Tech University [15062092-Y, 1206820-Y, 1206821-Y]
- Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci-Tech University
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1,2,3-Triazoles, as one of the most significant nitrogen-containing heterocycles due to their extensive use in biology, material science and organic synthesis, have aroused great interest. 1,2,3-Triazoles are commonly synthesized by metal-catalyzed azide-alkyne cycloaddition and organocatalytic azide-carbonyl cycloaddition, which indispensably employ the toxic and potentially explosive azides. The azide-free synthetic approaches provide a powerful and straightforward alternative to the assembly of diverse 1,2,3-triazoles without the use of azides. In this review, we summarize the recent development of the construction of 1,2,3-triazoles under azide-free conditions.
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