Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 94, Pages 12665-12667Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08153g
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Funding
- National Natural Science Foundation of China [21732005]
- excellent young scientist foundation of Sichuan University [2016SCU04A10]
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An asymmetric formal total synthesis of the akuammiline alkaloid (+)-strictamine is reported. The key features of the synthesis include a Friedel-Crafts cyclization to form the D-ring and the critical C7 all-carbon quaternary carbon centre, as well as an aza-1,6-conjugate addition to assemble the 2-azabicyclo[3.3.1] nonane system.
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