4.5 Article

Impact of drying conditions and wet film properties on adhesion and film solidification of lithium-ion battery anodes

Journal

DRYING TECHNOLOGY
Volume 35, Issue 15, Pages 1807-1817

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/07373937.2016.1276584

Keywords

Adhesion; coatings; film solidification; graphite anode; lithium-ion battery

Funding

  1. German Research Foundation (DFG) [SCHA 1266/9-1]
  2. Federal Ministry of Economic Affairs and Energy (BMWI) based on a parliamentary resolution of the Deutsche Bundestag [03ET6016]

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Electrodes constitute a vital component of lithium-ion battery cells. The property-determining, porous microstructure of anodes, which is composed of micrometer-sized graphite particles and nanoscale additives, was developed during convective removal of the solvent. In the present work, the impact of significant drying conditions and wet film properties, such as drying rate, slurry composition or active material particle size, just to name a few, is examined to provide further understanding of film solidification. The influence on both adhesion and film solidification is investigated. Subsequently, a previously developed film solidification mechanism will be critically reviewed based on findings.

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