4.7 Article

Design and synthesis of Co-N-C porous catalyst derived from metal organic complexes for highly effective ORR

Journal

DALTON TRANSACTIONS
Volume 46, Issue 45, Pages 15646-15650

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt03279j

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Funding

  1. Chongqing Key Laboratory for Advanced Materials and Technologies of Clean Energies
  2. Program for Innovation Team Building at Institutions of Higher Education in Chongqing [CXTDX201601011]
  3. Program for Excellent Talents in Chongqing [10206020600218]

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In this work, we reported a novel and slack rose-like metal organic precursor designed by coordinating p-phenylenediamine with cobalt ion. After subsequent pyrolysis and acid etching process, the as-prepared Co-N-C catalyst delivered a superior catalytic activity and long-term durability. Further applied in the Zn-air battery, it also displayed a comparable performance with 20% Pt/C.

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