Journal
CHEMSUSCHEM
Volume 10, Issue 23, Pages 4695-4698Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201701648
Keywords
boranes; borasiloxanes; green chemistry; main group elements; silicon
Funding
- National Science Centre [UMO-2015/19/B/ST5/00240]
- Poznan City Hall stipend for young researchers
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This paper demonstrates the first highly chemoselective syntheses of various borasiloxanes from hydroboranes and silanols, achieved through catalyst-free dehydrogenative coupling at room temperature. This green protocol, which uses easily accessible reagents, allows for the obtaining of borasiloxanes under air atmosphere and solvent-free conditions.
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