Journal
CHEMSUSCHEM
Volume 10, Issue 23, Pages 4764-4770Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201701437
Keywords
carbon dioxide; fischer-tropsch synthesis; fuels; hydrogenation; spinel phases
Funding
- Climate Change Response project [2015M1A2A2074663, 2015M1A2A2056824]
- Korea Center for Artificial Photosynthesis (KCAP) - MSIP [2009-0093880]
- MOTIE of Republic of Korea [10050509, KIAT N0001754]
- [NRF-2015R1A2A1A10054346]
- Korea Evaluation Institute of Industrial Technology (KEIT) [N0001754] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [10Z20130000001, 2015M1A2A2074663] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A microwave-assisted hydrothermal synthesis produces ZnFe2O4 containing Na residue as a precursor to a CO2 hydrogenation catalyst that displays high CO2 conversion and high selectivity to liquid hydrocarbon products in the gasoline and diesel range with high olefin-to-paraffin ratios. Compared to reference catalysts derived from Fe2O3 and a ZnO-Fe2O3 physical mixture, the ZnFe2O4-derived catalyst contains well-dispersed iron particles with Zn serving as a structural promoter. A profound effect of the residual Na as an electronic promoter is also observed, which improves the selectivity for C5+ hydrocarbons and olefins. The ZnFe2O4-derived catalyst exhibits excellent performance in the CO2 Fischer-Tropsch reaction as it forms the active Hagg iron carbide (-Fe5C2) phase readily through the insitu carburization of iron.
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