4.8 Review

3D Laser Micro- and Nanoprinting: Challenges for Chemistry

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 50, Pages 15828-15845

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201704695

Keywords

adaptive materials; biodegradable structures; direct laser writing; photoresists; stimulated emission depletion

Funding

  1. Helmholtz Association
  2. Australian Research Council (ARC)
  3. German Research Council (DFG)
  4. Karlsruhe School of Optics (KSOP)
  5. German Federal Ministry of Education and Research (BMBF)
  6. [SFB 1176]

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3D printing is a powerful emerging technology for the tailored fabrication of advanced functional materials. This Review summarizes the state-of-the art with regard to 3D laser micro- and nanoprinting and explores the chemical challenges limiting its full exploitation: from the development of advanced functional materials for applications in cell biology and electronics to the chemical barriers that need to be overcome to enable fast writing velocities with resolution below the diffraction limit. We further explore chemical means to enable direct laser writing of multiple materials in one resist by highly wavelength selective (-orthogonal) photochemical processes. Finally, chemical processes to construct adaptive 3D written structures that are able to respond to external stimuli, such as light, heat, pHvalue, or specific molecules, are highlighted, and advanced concepts for degradable scaffolds are explored.

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