4.7 Article

Vanadium recovery from stone coal through roasting and flotation

Journal

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(17)60022-0

Keywords

vanadium-bearing stone coal; roasting decarburization; mineralogy; preferential grinding; flotation

Funding

  1. National Key Technology R&D Program during the 12th Five-year Plan Period, China [2015BAB03B05]
  2. National Natural Science Foundation of China [51404177]

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A new process for vanadium recovery from stone coal by roasting-flotation was investigated based on the mineralogy. The process comprised four key steps: decarburization, preferential grinding, desliming and flotation. In the decarburization stage, roasting at 550 degrees C effectively avoided the negative effect of the carbonaceous materials in raw ore and generation of free CaO from calcite decomposition during roasting. Through preferential grinding, the high acid-consuming minerals were enriched in the middle fractions, while mica was enriched in the fine and coarse fractions. Through flotation, the final concentrate can be obtained with V2O5 grade of 1.07% and recovery of 83.30%. Moreover, the vanadium leaching rate of the final concentrate increased 13.53% compared to that of the feed. The results reveal that the decarburization by roasting at 550 degrees C is feasible and has little negative impact on mica flotation, and vanadium recovery from stone coal is conducive to reducing handling quantity, acid consumption and production cost.

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