4.8 Article

Electrical Homogeneity of Large-Area Chemical Vapor Deposited Multilayer Hexagonal Boron Nitride Sheets

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 46, Pages 39895-39900

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b09417

Keywords

hexagonal boron nitride; chemical vapor deposition; electrical homogeneity; conductive AFM; polycrystalline

Funding

  1. Ministry of Education of China
  2. National Natural Science Foundation of China [61502326, 41550110223, 11661131002]
  3. Jiangsu Government [BK20150343]
  4. Ministry of Finance of China [SX21400213]
  5. Chinese Ministry of Science and Technology [2015CB932700]
  6. STC Center for Integrated Quantum Materials, NSF [DMR-1231319]
  7. NSF [DMR/ECCS-1509197]
  8. SUTD-MIT
  9. Direct For Mathematical & Physical Scien
  10. Division Of Materials Research [1509197] Funding Source: National Science Foundation

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Large-area hexagonal boron nitride (h-BN) can be grown on polycrystalline metallic substrates via chemical vapor deposition (CVD), but the impact of local inhomogeneities on the electrical properties of the h-BN and their effect in electronic devices is unknown. Conductive atomic force microscopy (CAFM) and probe station characterization show that the tunneling current across the h-BN stack fluctuates up to 3 orders of magnitude from one substrate (Pt) grain to another. Interestingly, the variability in the tunneling current across the h-BN within the same substrate grain is very low, which may enable the use of CVD-grown h-BN in ultra scaled technologies.

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