One-step Preparation of Carbon-based Solid Acid Catalyst from Water Hyacinth Leaves for Esterification of Oleic Acid and Dehydration of Xylose

Carbon-based solid acid catalysts were successfully obtained via one-step hydrothermal carbonization (HTC) of water hyacinth (WH) in the presence of p-toluenesulfonic acid (PTSA). Increasing the HTC temperature from 180 to 240 degrees C resulted in carbonaceous materials with increased sulfur content and less adsorbed water. The material obtained at 220 degrees C (WH-PTSA-220) contains the highest amount of acid sites and promotes the highest initial rate of two transformations, that is, methanolysis of oleic acid and dehydration of xylose to furfural. While all PSTA-treated WH catalysts gave comparable fatty acid conversions (approximate to 97%) and furfural yields (approximate to 60%) after prolonged reaction times, the WH-PTSA-240 system bearing a relatively low acid density maintains the most favorable reusability profile. Higher HTC temperatures (220-240 degrees C) improved the catalyst reusability profiles due to graphitization and hydrophobicity of the carbon surface. The catalyst systems derived herein from biomass may have potential applications in biorefining platforms, utilizing the conversion of waste biomass to chemicals.