Journal
CHEMICAL & PHARMACEUTICAL BULLETIN
Volume 65, Issue 12, Pages 1185-1190Publisher
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.c17-00596
Keywords
organocatalyst; fluorous; conjugate addition; solvent-free
Funding
- Japan Society for the Promotion of Science (JSPS) KAKENHI [16K08178]
- Grants-in-Aid for Scientific Research [16K08178] Funding Source: KAKEN
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The novel fluorous organocatalyst bearing a diaminomethylenemalononitrile motif is prepared. The fluorous organocatalyst efficiently promotes asymmetric conjugate additions of ketones to nitroalkenes and results in high yields of these addition products with excellent enantioselectivities under solvent-free conditions.
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