Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 35, Issue 11, Pages 1673-1677Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700191
Keywords
Beckmann rearrangement; oganocatalyst; ketoximes; amides
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Funding
- Shaanxi Provincial Key Laboratory Project [15JS004]
- Baoji University of Arts and Sciences [ZK15046]
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An efficient Beckmann rearrangement of ketoximes was developed using carbon tetrabromide/ triphenylphosphine as an organocatalyst without addition of any acids or metals. The reaction showed good functional group tolerance and gave various amides in moderate to good yields.
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