4.7 Article

Direct alkylheteroarylation of alkenes via photoredox mediated C-H functionalization

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 96, Pages 12946-12949

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06484e

Keywords

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Funding

  1. National Natural Science Foundation of China [21662045]
  2. Applied Basic Research Project of Yunnan [2016FB019]
  3. Applied Basic Research Key Project of Yunnan [2013A039]

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The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C-H functionalization pathway. The use of inexpensive ethers as radical precursors combined with a straightforward method makes this a practical approach.

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